ZIRAM | ICSC: 0348 (October 2005) |
Zinc dimethyldithiocarbamate (T-4)-bis(Dimethylcarbamodithioato-S,S')zinc |
CAS #: 137-30-4 |
UN #: 2771 |
EC Number: 205-288-3 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air. | NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust. | Use water spray, foam, powder, carbon dioxide. |
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Abdominal pain. Nausea. Vomiting. | Use local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | Redness. Pain. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. |
Eyes | Redness. Pain. | Wear safety goggles or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. Nausea. Vomiting. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. |
According to UN GHS Criteria Transportation |
STORAGE | |
Store in an area without drain or sewer access. Separated from acids and food and feedstuffs. Keep in a well-ventilated room. Well closed. | |
PACKAGING | |
Do not transport with food and feedstuffs. Marine pollutant. |
ZIRAM | ICSC: 0348 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: ((CH3)2NCS.S)2Zn / C6H12N2S4Zn |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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MAK: (inhalable fraction): 0.01 mg/m3; peak limitation category: I(2); sensitization of skin (SH); pregnancy risk group: C |
ENVIRONMENT |
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The substance is very toxic to aquatic organisms. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. |
NOTES |
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If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T+, N; R: 22-26-37-41-43-48/22-50/53; S: (1/2)-22-26-28-36/37/39-45-60-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations Ziram (FAO Meeting Report PL/1965/10/1) Ziram (FAO/PL:1967/M/11/1) Ziram (Pesticide residues in food: 1996 evaluations Part II Toxicological) Ziram (IARC Summary & Evaluation, Volume 53, 1991)