|VINYLIDENE CHLORIDE||ICSC: 0083 (April 2014)|
| CAS #: 75-35-4
| UN #: 1303 (stabilized)
|EC Number: 200-864-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Extremely flammable. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools.||Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|PREVENT GENERATION OF MISTS!|
|Inhalation||Cough. Dizziness. Drowsiness. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention.|
|Skin||Protective gloves.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness.||Wear safety spectacles or eye protection in combination with breathing protection.||Rinse with plenty of water (remove contact lenses if easily possible).|
|Ingestion||Abdominal pain. Further see Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Remove all ignition sources. Consult an expert! Personal protection: filter respirator for organic vapours of low boiling point adapted to the airborne concentration of the substance. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERExtremely flammable liquid and vapour
Toxic if swallowed
May be harmful if inhaled
May cause drowsiness or dizziness
May cause damage to liver and kidneys through prolonged or repeated exposure
Harmful to aquatic life
|Store only if stabilized. Fireproof. Keep in the dark. Cool. Separated from incompatible materials. See Chemical Dangers. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
Put breakable packaging into closed unbreakable container.
|VINYLIDENE CHLORIDE||ICSC: 0083|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C2H2Cl2 / H2C=CCl2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 5 ppm as TWA; A4 (not classifiable as a human carcinogen).
MAK: 8.0 mg/m3, 2 ppm; peak limitation category: II(2); carcinogen category: 3; pregnancy risk group: C.
EU-OEL: 8 mg/m3, 2 ppm as TWA; 20 mg/m3, 5 ppm as STEL
|The substance is harmful to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT use in the vicinity of a fire or a hot surface, or during welding.
Symbol: F+, Xn; R: 12-20-40; S: (2)-7-16-29-36/37-46; Note: D
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Vinylidene chloride (EHC 100, 1990) Vinylidene chloride (HSG 36, 1989) Vinylidene Chloride (IARC Summary & Evaluation, Volume 71, 1999)