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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames.
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Water spray, foam, powder, carbon dioxide.
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| EXPLOSION |
Above 63°C explosive vapour/air mixtures may be formed.
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Above 63°C use a closed system, ventilation, and explosion-proof electrical equipment.
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| EXPOSURE |
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| Inhalation |
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Ventilation.
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Fresh air, rest.
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| Skin |
Redness. Pain.
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Protective gloves.
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Rinse skin with plenty of water or shower.
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| Eyes |
Redness. Pain.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Then wash away with plenty of water.
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| EMERGENCY RESPONSE | STORAGE | |||||||
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Keep in the dark. Separated from strong oxidants.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: CLEAR COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: The substance can presumably form explosive peroxides. Reacts with strong oxidants. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. MAK not established. |
ROUTES OF EXPOSURE: The substance can be absorbed into the body through the skin, and by ingestion. INHALATION RISK: No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes and the skin. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 171°C Melting point: below -75°C Relative density (water = 1): 0.879 at 25°C Solubility in water, g/100 ml : 6 (moderate) Vapour pressure, kPa at 25°C: 0.187 Relative vapour density (air = 1): 4.55 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.007 Flash point: 63 °C c.c. Auto-ignition temperature: 260°C Explosive limits, vol% in air: 1.1 at 80 °C. - 8.4 at 145 °C Octanol/water partition coefficient as log Pow: 1.15 (calculated) Viscosity, mm^2/s at 25 °C: 2.9 | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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Check for peroxides prior to distillation; eliminate if found. Card has been partially updated in : see Physical Properties.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations