IMAZALIL (ICSC)

IMAZALIL	ICSC: 1303

Date of peer-review: November 1998

Allyl 1-(2,4-dichlorophenyl)-2-imidazol-1-ylethyl ether
1-(2-(2,4-Dichlorophenyl)-2-(2-propenyloxy)ethyl)-1H-imidazole
Enilconazole

CAS #	35554-44-0	C₁₄H₁₄Cl₂N₂O
RTECS #	NI4776000	Molecular mass: 297.2
UN #
EC #	613-042-00-5

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Powder, water spray, foam, carbon dioxide.
EXPLOSION

EXPOSURE
Inhalation			Fresh air, rest.
Skin		Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion	Nausea.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL

PACKAGING & LABELLING

Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. (Extra personal protection: chemical protection suit including self-contained breathing apparatus).

Do not transport with food and feedstuffs.
EU Classification
Symbol: Xn, N
R: 20/22-41-50/53
S: (2-)26-39-60-61
UN Classification

EMERGENCY RESPONSE

STORAGE

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities © IPCS, CEC 2001

SEE IMPORTANT INFORMATION ON BACK

IMAZALIL

ICSC: 1303

IMPORTANT DATA

PHYSICAL STATE; APPEARANCE:
LIGHT YELLOW TO BROWN CRYSTALLINE MASS (SOLIDIFIED OIL).

CHEMICAL DANGERS:
The substance decomposes on distillation or on burning producing toxic fumes of nitrogen oxides and chloride.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates severely the eyes.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the liver, resulting in impaired functions and tissue lesions.

PHYSICAL PROPERTIES

Boiling point: (estimated) 319-347°C
Melting point: 50°C
Relative density (water = 1): 1.2
Solubility in water, g/100 ml at 20°C: 0.14
Vapour pressure, Pa at 20°C: negligible

Flash point: 192°C
Octanol/water partition coefficient as log Pow: 4.56

ENVIRONMENTAL DATA

The substance is very toxic to aquatic organisms. Avoid release to the environment in circumstances different to normal use.

NOTES

If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s). Carrier solvents used in commercial formulations may change physical and toxicological properties. Bromazil, Deccozil, Fecundal, Florasan, Freshgard, Fungaflor, Fungazil, Imaverol, Impala, Magnate, Sanazil are trade names.

ADDITIONAL INFORMATION

LEGAL NOTICE

Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information

    See Also:
       Toxicological Abbreviations
       Imazalil (Pesticide residues in food: 1977 evaluations)
       Imazalil (Pesticide residues in food: 1980 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1984 evaluations)
       Imazalil (Pesticide residues in food: 1985 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1986 evaluations Part II Toxicology)
       Imazalil (Pesticide residues in food: 1991 evaluations Part II Toxicology)
       Imazalil (JMPR Evaluations 2000 Part II Toxicological)
       Imazalil (JMPR Evaluations 2001 Part II Toxicological)
       Imazalil (JMPR Evaluations 2005 Part II Toxicological)