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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: all extinguishing agents allowed.
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| EXPLOSION |
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| EXPOSURE |
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AVOID ALL CONTACT!
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| Inhalation |
Burning sensation. Cough. Shortness of breath. Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest. Half-upright position. Refer for medical attention.
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| Skin |
Skin burns. Pain. Blisters.
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Protective clothing.
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Rinse with plenty of water, do NOT remove clothes. Refer for medical attention.
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| Eyes |
Redness. Pain. Severe deep burns.
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Face shield or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Abdominal pain. Burning sensation. Shock or collapse.
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Do not eat, drink, or smoke during work. Wash hands before eating.
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Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Rest. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place (extra personal protection: complete protective clothing including self-contained breathing apparatus).
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| EMERGENCY RESPONSE | STORAGE | |||||||
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Separated from strong acids. Dry. Well closed. | |||||||
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS TO WHITE CRYSTALS. CHEMICAL DANGERS: The substance decomposes on heating producing toxic and corrosive fumes including phosphorous oxides. The solution in water is a strong base, it reacts violently with acid and is corrosive. Attacks many metals in presence of water. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance is corrosive to the eyes, the skin and the respiratory tract. Corrosive on ingestion. Inhalation of dust may cause lung oedema (see Notes). | ||
| PHYSICAL PROPERTIES | |||
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Melting point (decomposes): 75°C Relative density (water = 1): 2.5 Solubility in water, g/100 ml: 8.8 |
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| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations