|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE FIGHTING|
|FIRE||Extremely flammable.||NO open flames, NO sparks and NO smoking.||Use powder, AFFF, foam, carbon dioxide.|
|EXPLOSION||Vapour/air mixtures are explosive.||Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling.||In case of fire: keep drums, etc., cool by spraying with water.|
|Inhalation||Cough. Dizziness. Drowsiness. Headache. Shortness of breath. Sore throat. Irregular heartbeat.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Refer for medical attention.|
|Skin||Dry skin. Redness.||Protective gloves.||Remove contaminated clothes. Rinse skin with plenty of water or shower.|
|Eyes||Redness. Pain.||Wear safety spectacles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Nausea. Vomiting. Further see Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Refer for medical attention .|
|PACKAGING & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
Symbol: F+, Xn, N; R: 12-51/53-65-66-67; S: (2)-9-16-29-33-61-62
UN Hazard Class: 3; UN Pack Group: I
|EMERGENCY RESPONSE||SAFE STORAGE|
Transport Emergency Card: TEC (R)-30S1265 or 30GF1-I+II.
NFPA Code: H1; F4; R0.
|Fireproof. Well closed.|
Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Boiling point: 28°C
Melting point: -160°C
Relative density (water = 1): 0.6
Solubility in water: none
Vapour pressure, kPa at 20°C: 79
Relative vapour density (air = 1): 2.5
Relative density of the vapour/air-mixture at 20°C (air = 1): 2.2
Flash point: <-51°C c.c.
Auto-ignition temperature: 420°C
Explosive limits, vol% in air: 1.4-7.6
Octanol/water partition coefficient as log Pow: 2.3
|The substance is harmful to aquatic organisms.|
Use of alcoholic beverages enhances the harmful effect.
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
Check oxygen content before entering area.
The relation between odour and the occupational exposure limit cannot be indicated.
Card has been partly updated in April 2005.
See sections Occupational Exposure Limits, EU classification, Emergency Response.
See Also: Toxicological Abbreviations