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Date of peer-review: April 2000
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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Gives off irritating or toxic fumes (or gases) in a fire. See Notes.
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NO open flames.
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Water spray, powder.
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| EXPLOSION |
Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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PREVENT DISPERSION OF DUST! STRICT HYGIENE!
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| Inhalation |
Cough. Shortness of breath. Sore throat. Wheezing.
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Local exhaust or breathing protection.
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Fresh air, rest. Refer for medical attention.
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| Skin |
Redness. Pain.
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
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| Eyes |
Redness. Pain.
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Safety goggles, or eye protection in combination with breathing protection if powder.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Diarrhoea. Weakness.
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Do not eat, drink, or smoke during work. Wash hands before eating.
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Rinse mouth. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Remove all ignition sources. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. (Extra personal protection: P2 filter respirator for harmful particles).
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EU Classification UN Classification UN Hazard Class: 4.1 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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Transport Emrgency Card: TEC (R)-41G15.
NFPA Code: H 1; F 2; R 0;
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Separated from strong oxidants. Well closed.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: BROWN AMORPHOUS OR BLUISH-RED SOLID. PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. CHEMICAL DANGERS: Upon heating, toxic fumes are formed. Reacts with strong oxidants. OCCUPATIONAL EXPOSURE LIMITS: TLV not established. |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. EFFECTS OF SHORT-TERM EXPOSURE: The aerosol irritates the eyes and the respiratory tract. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. | ||
| PHYSICAL PROPERTIES | |||
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Melting point: 140°C Density: 0.9 g/cm^3 Solubility in water: none |
Auto-ignition temperature: 276°C | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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Cobalt naphthenate is used as a solution usually in mineral oils and spirits: 6% (cobalt) solution; boiling point: >150°C; specific gravity (water=1): 0.94-0.98; vapour density (air=1): 4.9. Health effects of exposure to the substance have not been investigated adequately.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2001 | |||
See Also:
Toxicological Abbreviations