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COBALT NAPHTHENATE ICSC: 1093
Date of peer-review: April 2000

Naphthenic acid, cobalt salt
Naftolite
CAS # 61789-51-3 Co(C11H10O2)2
RTECS # QK8925000 Molecular mass: 407
UN # 2001
EC #
TYPES OF HAZARD / EXPOSURE ACUTE HAZARDS / SYMPTOMS PREVENTION FIRST AID / FIRE FIGHTING
FIRE Gives off irritating or toxic fumes (or gases) in a fire. See Notes.
NO open flames.
Water spray, powder.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!

Inhalation Cough. Shortness of breath. Sore throat. Wheezing.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
Skin Redness. Pain.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Redness. Pain.
Safety goggles, or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Diarrhoea. Weakness.
Do not eat, drink, or smoke during work. Wash hands before eating.
Rinse mouth. Refer for medical attention.
SPILLAGE DISPOSAL PACKAGING & LABELLING
Remove all ignition sources. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. (Extra personal protection: P2 filter respirator for harmful particles).
EU Classification
UN Classification
UN Hazard Class: 4.1
UN Pack Group: III
EMERGENCY RESPONSE STORAGE
Transport Emrgency Card: TEC (R)-41G15. NFPA Code: H 1; F 2; R 0;
Separated from strong oxidants. Well closed.
IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities © IPCS, CEC 2001

SEE IMPORTANT INFORMATION ON BACK


COBALT NAPHTHENATE ICSC: 1093
IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
BROWN AMORPHOUS OR BLUISH-RED SOLID.

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
Upon heating, toxic fumes are formed. Reacts with strong oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

EFFECTS OF SHORT-TERM EXPOSURE:
The aerosol irritates the eyes and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact may cause skin sensitization.
PHYSICAL PROPERTIES
Melting point: 140°C
Density: 0.9 g/cm^3
Solubility in water: none
Auto-ignition temperature: 276°C
ENVIRONMENTAL DATA

NOTES
Cobalt naphthenate is used as a solution usually in mineral oils and spirits: 6% (cobalt) solution; boiling point: >150°C; specific gravity (water=1): 0.94-0.98; vapour density (air=1): 4.9. Health effects of exposure to the substance have not been investigated adequately.
ADDITIONAL INFORMATION


LEGAL NOTICE Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information
© IPCS, CEC 2001


    See Also:
       Toxicological Abbreviations