|CAS #: 76-06-2||Chloropicrin
| UN #: 1580
| EINECS #: 200-930-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Many reactions may cause fire or explosion.||In case of fire in the surroundings, use appropriate extinguishing media.|
|STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Abdominal pain. Cough. Diarrhoea. Dizziness. Headache. Nausea. Sore throat. Vomiting. Weakness. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Refer for medical attention.|
|Skin||Redness. Pain.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Blurred vision.||Wear safety spectacles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Personal protection: chemical protection suit including self-contained breathing apparatus.||
According to UN GHS Criteria
|Separated from food and feedstuffs. See Chemical Dangers. Cooled. Keep in the dark. Ventilation along the floor.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
TLV: 0.1 ppm as TWA; A4 (not classifiable as a human carcinogen).
MAK: 0.68 mg/m3, 0.1 ppm; peak limitation category: I(1)
|Depending on the degree of exposure, periodic medical examination is indicated.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation is therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT take working clothes home.
Symbol: T+; R: 22-26-36/37/38; S: (1/2)-36/37-38-45
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See Also: Toxicological Abbreviations