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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
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| EXPOSURE |
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PREVENT DISPERSION OF DUST! STRICT HYGIENE!
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| Inhalation |
Cough. Sore throat. See Ingestion.
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Ventilation (not if powder), local exhaust, or breathing protection.
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Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
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| Skin |
Redness. Pain.
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Protective gloves.
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Remove contaminated clothes. Rinse skin with plenty of water or shower.
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| Eyes |
Redness. Pain.
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Safety spectacles or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Abdominal cramps. Convulsions. Dullness. Unconsciousness. Vomiting.
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Do not eat, drink, or smoke during work. Wash hands before eating.
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Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment.
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Do not transport with food and feedstuffs. EU Classification Symbol: T R: 20-25 S: (1/2-)45 UN Classification UN Hazard Class: 6.1 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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Transport Emergency Card: TEC (R)-61S1564-III or 61GT5-III
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Separated from food and feedstuffs. Store in an area without drain or sewer access.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: ODOURLESS COLOURLESS CRYSTALS OCCUPATIONAL EXPOSURE LIMITS: TLV: (as Ba) 0.5 mg/m³ as TWA; A4 (not classifiable as a human carcinogen); (ACGIH 2004). EU OEL: (as Ba) 0.5 mg/m³ as TWA (EU 2006). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes, the skin and the respiratory tract. The substance may cause effects on the nervous system. Exposure could cause hypokalaemia , resulting in cardiac disordersand muscular disorders. Exposure may result in death. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 1560°C Melting point: 960°C Density: 3.9 g/cm³ Solubility in water, g/100 ml: 36 (good) |
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| ENVIRONMENTAL DATA | |||
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The substance is harmful to aquatic organisms.
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| NOTES | |||
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Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Card has been partially updated in October 2005: see Occupational Exposure Limits, Emergency Response. Card has been partially updated in April 2010: see Occupational Exposure Limits, Spillage Disposal, Storage.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations