|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE FIGHTING|
|FIRE||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Heating will cause rise in pressure with risk of bursting.||NO open flames.||Use water spray, foam, powder, carbon dioxide.|
|EXPOSURE||AVOID ALL CONTACT!|
|Inhalation||Cough. Sore throat. Burning sensation.||Use closed system.||Fresh air, rest. Half-upright position. Refer immediately for medical attention.|
|Skin||Redness. Pain. Serious skin burns.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.|
|Ingestion||Sore throat. Burning sensation. Abdominal pain.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .|
|PACKAGING & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Treat remaining liquid with a mixture of ammonia (4-8%), detergent (2%), and water. Do NOT let this chemical enter the environment.||
Do not transport with food and feedstuffs.
Symbol: T, N; R: 23-36/37/38-42/43-51/53; S: (1/2)-26-28-38-45-61; Note: 2
UN Hazard Class: 6.1; UN Pack Group: III
Fatal if inhaled
Harmful in contact with skin
Causes severe skin burns and eye damage
Causes serious eye irritation
May cause allergic or asthmatic symptoms or breathing difficulties if inhaled
May cause allergic skin reaction
|EMERGENCY RESPONSE||SAFE STORAGE|
Transport Emergency Card: TEC (R)-61S2290 or 61GT1-III.
NFPA Code: H2; F1; R1; W.
|Separated from bases, acids, alcohols, amines, amides, phenols, mercaptans and food and feedstuffs. Keep in a well-ventilated room. Well closed. Cool. Dry. Store in an area without drain or sewer access.|
Physical State; Appearance
COLOURLESS-TO-YELLOW LIQUID WITH PUNGENT ODOUR.
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and through the skin.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Boiling point at 1.33kPa: 158°C
Decomposes at 310°C
Melting point: -60°C
Relative density (water = 1): 1.06
Solubility in water, g/100ml: 15 (reaction)
Vapour pressure, Pa at 20°C: 0.04
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.0
Flash point: 155°C c.c.
Auto-ignition temperature: 430°C
Explosive limits, vol% in air: 0.7-4.5
Octanol/water partition coefficient as log Pow: 4.75 (calculated)
|This substance may be hazardous to the environment. Special attention should be given to aquatic organisms.|
Anyone who has shown symptoms of asthma due to this substance should avoid all further contact.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT take working clothes home.
See Also: Toxicological Abbreviations