|CAS #: 590-18-1||2-Butene, (Z)-
| UN #: 1012
| EINECS #: 209-673-7
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Extremely flammable. Gas/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding) if in liquid state. Use non-sparking handtools. Flame arrester to prevent flash-back from burner to cylinder.||Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Dizziness. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||ON CONTACT WITH LIQUID: FROSTBITE.||Cold-insulating gloves.||ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .|
|Eyes||See Skin.||Wear face shield.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Do not eat, drink, or smoke during work.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. NEVER direct water jet on liquid.||
According to UN GHS Criteria
|Fireproof. Store outside or in a separate well-ventilated building. Cool.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C4H8 / CH3-HC=CH-CH3
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|TLV: 250 ppm as TWA|
|High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
Check oxygen content before entering area.
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
The recommendations on this Card also apply to trans-2-butene (ICSC 0398).
Symbol: F+; R: 12; S: (2)-9-16-33; Note: C
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations