|CAS #: 110-86-1||Azine
| UN #: 1282
| EINECS #: 203-809-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.||Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Cough. Dizziness. Headache. Nausea. Shortness of breath. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Burning sensation. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear safety spectacles or face shield.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Diarrhoea. Vomiting. Weakness. Further see Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: self-contained breathing apparatus. Remove all ignition sources. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Fireproof. Separated from strong oxidants and strong acids. Cool. Dry. Well closed.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
TLV: 1 ppm as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: skin absorption (H); carcinogen category: 3B
|The substance is harmful to aquatic organisms.|
|Pyridine can normally be detected by odour at levels well below the TLV.
However, perception of the odour may decline quickly.
Depending on the degree of exposure, periodic medical examination is suggested.
Symbol: F, Xn; R: 11-20/21/22; S: (2)-26-28
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Pyridine (IARC Summary & Evaluation, Volume 77, 2000)