|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE FIGHTING|
|FIRE||Combustible. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames.||Use dry powder, foam, carbon dioxide.|
|EXPOSURE||PREVENT GENERATION OF MISTS!|
|Inhalation||Cough. Sore throat. Shortness of breath.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention.|
|Skin||Redness. Pain.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Burns.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.|
|Ingestion||Cough. Sore throat.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Seek medical attention if you feel unwell.|
|PACKAGING & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.||
Do not transport with food and feedstuffs.
Symbol: T; R: 45-22-23-37/38-41; S: 53-45; Note: E
UN Hazard Class: 8; UN Pack Group: II
Fatal if inhaled vapour
Harmful if swallowed
Causes skin irritation
Causes serious eye damage
Suspected of causing genetic defects
May cause cancer
May cause respiratory irritation
Causes damage to the lungs through prolonged or repeated exposure if inhaled
May cause damage to liver, kidneys and thyroid through prolonged or repeated exposure if swallowed
May be harmful if swallowed and enters airways
|EMERGENCY RESPONSE||SAFE STORAGE|
Transport Emergency Card: TEC (R)-80S2226 or 80GC9-II+III].
NFPA Code: H4; F1; R0.
|Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry. Well closed. Ventilation along the floor.|
Physical State; Appearance
COLOURLESS-TO-YELLOW FUMING OILY LIQUID WITH PUNGENT ODOUR.
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Boiling point: 221°C
Melting point: -5°C
Relative density (water = 1): 1.4
Solubility in water: reaction
Vapour pressure, Pa at 20°C: 20
Relative vapour density (air = 1): 6.8
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00
Flash point: 108°C c.c.
Auto-ignition temperature: 211°C
Octanol/water partition coefficient as log Pow: 2.92
Viscosity: 1.7 mm²/s at 20°C
Combustible vapour/air mixtures difficult to ignite, may be developed under certain conditions.
The occupational exposure limit value should not be exceeded during any part of the working exposure.
Depending on the degree of exposure, periodic medical examination is suggested.
Refer for medical attention if breathing difficulties and/or fever develop.
See Also: Toxicological Abbreviations Benzotrichloride (IARC Summary & Evaluation, Volume 29, 1982)