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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Flammable. Gives off irritating or toxic fumes (or gases) in a fire.
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NO open flames, NO sparks, and NO smoking.
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Dry powder. Foam. Carbon dioxide.
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| EXPLOSION |
Above 31°C explosive vapour/air mixtures may be formed. See Notes.
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Above 31°C use a closed system, ventilation, and explosion-proof electrical equipment.
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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STRICT HYGIENE!
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| Inhalation |
Dizziness. Drowsiness. Headache. Nausea. Vomiting. Weakness. Unconsciousness.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest. Refer for medical attention.
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| Skin |
Redness. Pain.
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Protective clothing. Protective gloves.
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Remove contaminated clothes. Rinse and then wash skin with water and soap.
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| Eyes |
Redness. Pain.
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Safety goggles, or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Nausea. Vomiting.
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Do not eat, drink, or smoke during work.
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Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Rest.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
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Airtight. Marine pollutant. Note: D EU Classification Symbol: Xn R: 10-20-36/38 S: (2-)23 UN Classification UN Hazard Class: 3 UN Pack Group: III GHS Classification Danger Flammable liquid and vapour Harmful if inhaled vapour Causes skin irritation Causes eye irritation Suspected of causing cancer Causes damage to central nervous system and liver through prolonged or repeated exposure Toxic to aquatic life | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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Transport Emergency Card: TEC (R)-30S2055; 30GF1-III-9 NFPA Code: H 2; F 3; R 2;
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Fireproof. Separated from incompatible materials See Chemical Dangers. Cool. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS TO YELLOW OILY LIQUID. CHEMICAL DANGERS: The substance can form explosive peroxides. The substance may polymerize due to warming, under the influence of light, oxidants oxygen, and peroxides , causing fire and explosion hazard. Reacts violently with strong acids, strong oxidants causing fire and explosion hazard. Attacks rubber, copper and copper alloys. OCCUPATIONAL EXPOSURE LIMITS: TLV: 20 ppm as TWA; 40 ppm as STEL; A4 (not classifiable as a human carcinogen); BEI issued (ACGIH 2005). MAK: 20 ppm, 86 mg/m³; Peak limitation category: II(2); Carcinogen category: 5; Pregnancy risk group: C; BAT issued; (DFG 2006). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour. INHALATION RISK: A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes, the skin and the respiratory tract. Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis. The substance may cause effects on the central nervous system. Exposure at high levels may result in unconsciousness. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The liquid defats the skin. The substance may have effects on the central nervous system. Exposure to the substance may enhance hearing damage caused by exposure to noise. This substance is possibly carcinogenic to humans. See Notes. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 145°C Melting point: -30.6°C Relative density (water = 1): 0.91 Solubility in water, g/100 ml at 20°C: 0.03 Vapour pressure, kPa at 20°C: 0.67 Relative vapour density (air = 1): 3.6 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.02 Flash point: 31°C c.c. Auto-ignition temperature: 490°C Explosive limits, vol% in air: 0.9-6.8 Octanol/water partition coefficient as log Pow: 3.0 | ||
| ENVIRONMENTAL DATA | |||
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The substance is toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment.
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| NOTES | |||
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Depending on the degree of exposure, periodic medical examination is indicated. Check for peroxides prior to distillation; eliminate if found. Styrene monomer vapours are uninhibited and may form polymers in vents or flame arresters of storage tanks, resulting in blockage of vents. Do NOT take working clothes home. Card has been partially updated in 2007: see Occupational Exposure Limits, Fire fighting.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations
Styrene (EHC 26, 1983)
Styrene (WHO Food Additives Series 19)
STYRENE (JECFA Evaluation)
Styrene (PIM 509)
Styrene (IARC Summary & Evaluation, Volume 60, 1994)
Styrene (IARC Summary & Evaluation, Volume 82, 2002)