ICSC 0058 - DICHLOROMETHANE

DICHLOROMETHANE

ICSC: 0058
_{Peer-Review Status: 04.12.2000 Validated}

Methylene chloride
DCM

CAS #: 75-09-2 RTECS #: PA8050000
UN #: 1593
EC #: 602-004-00-3
EINECS #: 200-838-9

Formula: CH₂Cl₂
Molecular mass: 84.9

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Combustible under specific conditions. Gives off irritating or toxic fumes (or gases) in a fire.		In case of fire in the surroundings, use appropriate extinguishing media.
EXPLOSION	Risk of fire and explosion. See Chemical Dangers.	Prevent build-up of electrostatic charges (e.g., by grounding).	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE		PREVENT GENERATION OF MISTS! STRICT HYGIENE!
Inhalation	Dizziness. Drowsiness. Headache. Nausea. Weakness. Unconciousness. Death	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Skin	Dry skin. Redness. Burning sensation.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness. Pain. Severe deep burns.	Wear safety goggles, face shield or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Abdominal pain. Further see Inhalation.	Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Rest.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	Do not transport with food and feedstuffs. EC Classification Symbol: Xn; R: 40; S: (2)-23-24/25-36/37 UN Classification UN Hazard Class: 6.1; UN Pack Group: III GHS Classification

EMERGENCY RESPONSE	SAFE STORAGE
Transport Emergency Card: TEC (R)-61S1593. NFPA Code: H2; F1; R0.	Separated from metals and food and feedstuffs. See Chemical Dangers. Cool. Ventilation along the floor.

IMPORTANT DATA

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers
The vapour is heavier than air. As a result of flow, agitation, etc., electrostatic charges can be generated.

Chemical dangers
Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes. Reacts with metals such as aluminium powder and magnesium powder, strong bases and strong oxidants. This generates fire and explosion hazard. Attacks some forms of plastic, rubber and coatings.

Occupational exposure limits
TLV: 50ppm as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans); BEI issued; (ACGIH 2004).
MAK: Carcinogen category: 3A; (DFG 2004).

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.

Effects of short-term exposure
The substance is irritating to the eyes, skin and respiratory tract. Exposure could cause lowering of consciousness. Exposure could cause formation of methaemoglobin.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the central nervous system and liver. This substance is possibly carcinogenic to humans.

PHYSICAL PROPERTIES	ENVIRONMENTAL DATA
Boiling point: 40°C Melting point: -95.1°C Relative density (water = 1): 1.3 Solubility in water, g/100ml at 20°C: 1.3 Vapour pressure, kPa at 20°C: 47.4 Relative vapour density (air = 1): 2.9 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.9 Auto-ignition temperature: 556°C Explosive limits, vol% in air: 12-25 Octanol/water partition coefficient as log Pow: 1.25	This substance may be hazardous to the environment. Special attention should be given to ground water contamination.

NOTES

Addition of small amounts of a flammable substance or an increase in the oxygen content of the air strongly enhances combustibility.
Depending on the degree of exposure, periodic medical examination is suggested.
The odour warning when the exposure limit value is exceeded is insufficient.
Do NOT use in the vicinity of a fire or a hot surface, or during welding.
R30 is a trade name.
Card has been partly updated in April 2005.
See section Occupational Exposure Limits.

ADDITIONAL INFORMATION

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004-2012

LEGAL NOTICE

Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

    See Also:
       Toxicological Abbreviations
       Dichloromethane (FAO Nutrition Meetings Report Series 48a)
       Dichloromethane (WHO Food Additives Series 30)
       DICHLOROMETHANE (JECFA Evaluation)
       Dichloromethane (IARC Summary & Evaluation, Volume 71, 1999)