|ALLYL CHLORIDE||ICSC: 0010|
|CAS #: 107-05-1||3-Chloro-1-propene
| UN #: 1100
| EINECS #: 203-457-6
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive. Risk of fire and explosion on contact with incompatible substances. See Chemical Dangers.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.||Use powder, AFFF, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Cough. Sore throat. Headache. Dizziness. Weakness. Laboured breathing. Vomiting. Unconsciousness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Redness. Burning sensation. Pain.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain. Blurred vision.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Burning sensation. Vomiting.||Do not eat, drink, or smoke during work.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
According to UN GHS Criteria
|Fireproof. Separated from food and feedstuffs and incompatible materials. See Chemical Dangers. Dry.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|ALLYL CHLORIDE||ICSC: 0010|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C3H5Cl / CH2=CHCH2Cl
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
TLV: 1 ppm as TWA; 2 ppm as STEL; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: skin absorption (H); carcinogen category: 3B
|The substance is harmful to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.
Symbol: F, Xn, N; R: 11-20/21/22-36/37/38-40-48/20-68-50; S: (2)-16-25-26-36/37-46-61; Note: D
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations Allyl Chloride (IARC Summary & Evaluation, Volume 36, 1985) Allyl Chloride (IARC Summary & Evaluation, Volume 71, 1999)