ICSC 1575 - CYCLOTETRAMETHYLENE TETRANITRAMINE

CYCLOTETRAMETHYLENE TETRANITRAMINE	ICSC: 1575 (April 2005)
HMX Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine Octogen

CAS #: 2691-41-0

UN #: 0226 (wet) UN #: 0484 (desensitized)

EC Number: 220-260-0

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion. Explosive.	NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT expose to friction or shock.	In case of fire in the surroundings, use appropriate extinguishing media. Combat fire from a sheltered position.


	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	See Ingestion.	Use ventilation (not if powder), local exhaust or breathing protection.	Fresh air, rest.
Skin	MAY BE ABSORBED! Redness.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness. Pain.	Wear safety spectacles or eye protection in combination with breathing protection if powder.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Confusion. Drowsiness. Convulsions. Unconsciousness.	Do not eat, drink, or smoke during work.	Rinse mouth. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Evacuate danger area! Consult an expert! Remove all ignition sources. Personal protection: chemical protection suit. Cover the spilled material with water. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Do NOT let this chemical enter the environment.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 1.1D; UN Pack Group: II
STORAGE
Fireproof. Separated from strong bases and strong acids. Store in an area without drain or sewer access.
PACKAGING

CYCLOTETRAMETHYLENE TETRANITRAMINE

ICSC: 1575

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS CRYSTALS. Physical dangers As a result of flow, agitation, etc., electrostatic charges can be generated. Dust explosion possible if in powder or granular form, mixed with air. Chemical dangers Heating may cause violent combustion or explosion. May decompose explosively on shock, friction or concussion. Decomposes on heating. This produces toxic gases including nitrogen oxides. Reacts violently with acids and bases.	Formula: C₄H₈N₈O₈ Molecular mass: 296.2 Melting point: 275°C Density: 1.9 g/cm³ Solubility in water: none Vapour pressure, Pa at 25°C: <0.1 Auto-ignition temperature: 234°C

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS CRYSTALS.

Physical dangers
As a result of flow, agitation, etc., electrostatic charges can be generated. Dust explosion possible if in powder or granular form, mixed with air.

Chemical dangers
Heating may cause violent combustion or explosion. May decompose explosively on shock, friction or concussion. Decomposes on heating. This produces toxic gases including nitrogen oxides. Reacts violently with acids and bases.

Formula: C₄H₈N₈O₈
Molecular mass: 296.2
Melting point: 275°C
Density: 1.9 g/cm³
Solubility in water: none
Vapour pressure, Pa at 25°C: <0.1
Auto-ignition temperature: 234°C

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. Effects of short-term exposure The substance is irritating to the eyes and skin. The substance may cause effects on the central nervous system. This may result in irritability, convulsions and lowering of consciousness. Medical observation is indicated.	Inhalation risk A harmful concentration of airborne particles can be reached quickly when dispersed. Effects of long-term or repeated exposure The substance may have effects on the kidneys and liver.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

Effects of short-term exposure
The substance is irritating to the eyes and skin. The substance may cause effects on the central nervous system. This may result in irritability, convulsions and lowering of consciousness. Medical observation is indicated.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed.

Effects of long-term or repeated exposure
The substance may have effects on the kidneys and liver.

OCCUPATIONAL EXPOSURE LIMITS

ENVIRONMENT
This substance may be hazardous to the environment. Special attention should be given to aquatic organisms.

NOTES
Combustion in a confined space may turn into detonation. The substance may be transported only in water (15%) or desensitized with wax.

ADDITIONAL INFORMATION

EC Classification

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    See Also:
       Toxicological Abbreviations