|CHLOROACETYL CHLORIDE||ICSC: 0845 (March 1998)|
|Chloroacetic acid chloride
| CAS #: 79-04-9
| UN #: 1752
|EC Number: 201-171-6
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.||In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Laboured breathing. Burning sensation. Blue lips, fingernails and skin. Shortness of breath. Sore throat. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Pain. Serious skin burns. Blisters.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Pain. Redness. Blurred vision. Severe deep burns.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Burning sensation. Abdominal pain. Diarrhoea. Shock or collapse.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Do NOT induce vomiting. Give nothing to drink. Refer for medical attention . See Notes.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Cover the spilled material with dry sand. Collect leaking and spilled liquid in sealable containers as far as possible. Then store and dispose of according to local regulations. NEVER direct water jet on liquid. Personal protection: complete protective clothing including self-contained breathing apparatus.||
According to UN GHS Criteria
|Separated from food and feedstuffs. See Chemical Dangers. Dry. Keep in a well-ventilated room.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|CHLOROACETYL CHLORIDE||ICSC: 0845|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C2H2Cl2O / ClCH2COCl
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.05 ppm as TWA; 0.15 ppm as STEL; (skin).
MAK skin absorption (H)
|The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Do NOT take working clothes home.
Symbol: T, C, N; R: 14-23/24/25-35-48/23-50; S: (1/2)-7/8-9-26-36/37/39-45-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations