TRIPHENYLTIN HYDROXIDE | ICSC: 1283 (April 2005) |
Hydroxytriphenylstannane Hydroxytriphenylstannate Fentin hydroxide |
CAS #: 76-87-9 |
UN #: 2786 |
EC Number: 200-990-6 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Liquid formulations containing organic solvents may be flammable. | NO open flames. | Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
AVOID ALL CONTACT! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Dizziness. Drowsiness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | MAY BE ABSORBED! Redness. Pain. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . |
Eyes | Redness. Pain. Blurred vision. | Wear safety goggles or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. Further see Inhalation. | Do not eat, drink, or smoke during work. Wash hands before eating. | Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two glasses of water to drink. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: face shield, chemical protection suit and particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. |
According to UN GHS Criteria Transportation |
STORAGE | |
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. Severe marine pollutant. |
TRIPHENYLTIN HYDROXIDE | ICSC: 1283 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C18H16OSn / (C6H5)3SnOH |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: (as Sn): 0.1 mg/m3, as TWA; 0.2 mg/m3 as STEL; (skin); A4 (not classifiable as a human carcinogen). MAK: (as Sn): 0.002 mg/m3, 0.0004 ppm; peak limitation category: II(2); pregnancy risk group: C; skin absorption (H); carcinogen category: 4 |
ENVIRONMENT |
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The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur along the food chain, for example in fish and molluscs. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. |
NOTES |
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Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T+, N; R: 24/25-26-37/38-40-41-48/23-50/53-63; S: (1/2)-26-28-36/37/39-45-60-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations