1,3-DICHLOROPROPENE (MIXED ISOMERS) | ICSC: 0995 (April 2013) |
1,3-Dichloropropylene Dichloropropene 3-Chloroallyl chloride DCP |
CAS #: 542-75-6 |
UN #: 2047 |
EC Number: 208-826-5 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 25°C explosive vapour/air mixtures may be formed. | NO open flames, NO sparks and NO smoking. Above 25°C use a closed system, ventilation and explosion-proof electrical equipment. | Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
AVOID ALL CONTACT! PREVENT GENERATION OF MISTS! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Headache. Dizziness. Nausea. Vomiting. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | Redness. | Protective gloves. Protective clothing. | Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . |
Eyes | Redness. | Wear safety goggles or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. | Do not eat, drink, or smoke during work. | Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Ventilation. Remove all ignition sources. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable plastic containers as far as possible. Do NOT let this chemical enter the environment. |
According to UN GHS Criteria DANGER
Flammable liquid and vapourToxic if swallowed, in contact with skin or if inhaled Causes skin and eye irritation May cause an allergic skin reaction Suspected of causing cancer May cause respiratory irritation Causes damage to central nervous system Very toxic to aquatic life with long lasting effects Transportation |
STORAGE | |
Fireproof. Separated from metals and oxidants. Well closed. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. | |
PACKAGING | |
1,3-DICHLOROPROPENE (MIXED ISOMERS) | ICSC: 0995 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C3H4Cl2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 1 ppm as TWA; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans). MAK: skin absorption (H); sensitization of skin (SH); carcinogen category: 2 |
ENVIRONMENT |
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The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert. Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 10-20-24/25-36/37/38-43-65-50/53; S: (1/2)-36/37-45-60-61; Note: C, D |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations