p-ANISIDINE | ICSC: 0971 (April 2009) |
4-Aminoanisole 4-Methoxybenzenamine 1-Amino-4-methoxybenzene 4-Methoxyaniline |
CAS #: 104-94-9 |
UN #: 2431 |
EC Number: 203-254-2 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air. | NO open flames. Prevent deposition of dust. Closed system, dust explosion-proof electrical equipment and lighting. | Use water spray, foam, powder, carbon dioxide. |
PREVENT DISPERSION OF DUST! STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Blue lips, fingernails and skin. Dizziness. Headache. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | MAY BE ABSORBED! Further see Inhalation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. |
Eyes | Redness. | Wear face shield or eye protection in combination with breathing protection. | Rinse with plenty of water (remove contact lenses if easily possible). |
Ingestion | Nausea. Further see Inhalation. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Harmful if swallowedMay be harmful in contact with skin Causes damage to blood Causes damage to the blood through prolonged or repeated exposure Toxic to aquatic life Transportation |
STORAGE | |
Separated from strong oxidants, strong bases, acids, chloroformates and food and feedstuffs. Provision to contain effluent from fire extinguishing. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
p-ANISIDINE | ICSC: 0971 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C7H9NO / H2NC6H4OCH3 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 0.5 mg/m3, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued. MAK: skin absorption (H); carcinogen category: 3 |
ENVIRONMENT |
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The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. See ICSC 0970. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T+, N; R: 26/27/28-33-50; S: (1/2)-28-36/37-45-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations