o-TOLIDINE | ICSC: 0960 (April 2009) |
3,3'-Dimethyl-(1,1'-biphenyl)-4,4'-diamine Bianisidine 3,3'-Dimethylbenzidine 4,4'-Bi-o-toluidine |
CAS #: 119-93-7 |
EC Number: 204-358-0 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. | NO open flames. | Use powder, water spray, foam, carbon dioxide. |
See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE. PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Use closed system or ventilation. | Fresh air, rest. | |
Skin | MAY BE ABSORBED! See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. |
Eyes | Wear safety spectacles. | Rinse with plenty of water (remove contact lenses if easily possible). | |
Ingestion | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Give one or two glasses of water to drink. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. |
According to UN GHS Criteria WARNING
Harmful if swallowedSuspected of causing cancer Toxic to aquatic life Transportation |
STORAGE | |
Separated from strong oxidants and food and feedstuffs. Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
o-TOLIDINE | ICSC: 0960 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C14H16N2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: (skin); A3 (confirmed animal carcinogen with unknown relevance to humans). MAK: carcinogen category: 2 |
ENVIRONMENT |
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The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 45-22-51/53; S: 53-45-61; Note: E |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations