SELENIUM OXYCHLORIDE | ICSC: 0948 (March 2000) |
Selenium chloride oxide Seleninyl chloride |
CAS #: 7791-23-3 |
UN #: 2879 |
EC Number: 232-244-0 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. | In case of fire in the surroundings, use appropriate extinguishing media. |
STRICT HYGIENE! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Burning sensation. Cough. Laboured breathing. Sore throat. Shortness of breath. Symptoms may be delayed. See Notes. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. |
Skin | Redness. Pain. Blisters. Skin burns. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . |
Eyes | Redness. Pain. Severe deep burns. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Burning sensation. Sore throat. Nausea. Abdominal cramps. Vomiting. Abdominal pain. Diarrhoea. Shock or collapse. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Do NOT induce vomiting. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria Transportation |
STORAGE | |
Separated from metal oxides, strong bases and food and feedstuffs. Dry. Ventilation along the floor. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
SELENIUM OXYCHLORIDE | ICSC: 0948 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: SeOCl2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 0.2 mg/m3, as TWA. MAK: (as Se, inhalable fraction): 0.02 mg/m3; peak limitation category: II(8); skin absorption (H); carcinogen category: 3; pregnancy risk group: C |
ENVIRONMENT |
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The substance is harmful to aquatic organisms. |
NOTES |
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The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered. Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 23/25-33-50/53; S: (1/2)-20/21-28-45-60-61; Note: A |
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See Also: Toxicological Abbreviations