2,2-DICHLOROACETYL CHLORIDE | ICSC: 0869 (September 1997) |
Dichloroacetyl chloride |
CAS #: 79-36-7 |
UN #: 1765 |
EC Number: 201-199-9 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 66°C explosive vapour/air mixtures may be formed. | NO open flames. NO contact with water. Above 66°C use a closed system and ventilation. | Use powder, carbon dioxide. NO water. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. |
PREVENT GENERATION OF MISTS! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Symptoms may be delayed. See Notes. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. |
Skin | Pain. Redness. Blisters. Skin burns. | Protective gloves. Protective clothing. | First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention . |
Eyes | Pain. Redness. Severe deep burns. Loss of vision. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Burning sensation. Abdominal cramps. Shock or collapse. | Do not eat, drink, or smoke during work. | Rinse mouth. Do NOT induce vomiting. Give nothing to drink. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria Transportation |
STORAGE | |
Separated from strong oxidants, strong bases, food and feedstuffs, alcohols and water. Dry. Well closed. Keep in a well-ventilated room. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
2,2-DICHLOROACETYL CHLORIDE | ICSC: 0869 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C2HCl3O / Cl2CHCOCl |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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ENVIRONMENT |
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This substance may be hazardous to the environment. Special attention should be given to water quality. |
NOTES |
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Reacts violently with fire extinguishing agents such as water. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: C, N; R: 35-50; S: (1/2)-9-26-45-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations