DEMETON-S | ICSC: 0864 (April 2006) |
O,O-Diethyl S-2-ethylthioethyl phosphorothioate Demethonthiol |
CAS #: 126-75-0 |
UN #: 3018 |
EC Number: 204-801-8 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. | NO open flames. | Use foam, powder, carbon dioxide. |
PREVENT GENERATION OF MISTS! AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Dizziness. Nausea. Vomiting. Pupillary constriction, muscle cramp, excessive salivation. Laboured breathing. Convulsions. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. See Notes. |
Skin | MAY BE ABSORBED! Muscle twitching. Further see Inhalation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . |
Eyes | Redness. Redness. Pain. | Wear face shield. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal cramps. Diarrhoea. Further see Inhalation. | Do not eat, drink, or smoke during work. Wash hands before eating. | Give a slurry of activated charcoal in water to drink. Rest. Refer for medical attention . See Notes. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Fatal if swallowedCauses damage to nervous system Transportation |
STORAGE | |
Separated from food and feedstuffs. Dry. Keep in a well-ventilated room. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
DEMETON-S | ICSC: 0864 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C8H19O3PS2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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ENVIRONMENT |
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This substance may be hazardous to the environment. Special attention should be given to fish and bees. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. |
NOTES |
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Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Carrier solvents used in commercial formulations may change physical and toxicological properties. Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T+; R: 27/28; S: (1/2)-28-36/37-45 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations