CHLOROACETONITRILE | ICSC: 0844 (October 1999) |
Chloroethanenitrile Monochloroacetonitrile Chloromethyl cyanide |
CAS #: 107-14-2 |
UN #: 2668 |
EC Number: 203-467-0 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 47°C explosive vapour/air mixtures may be formed. | NO open flames, NO sparks and NO smoking. Above 47°C use a closed system and ventilation. | Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Sore throat. Cough. Headache. Laboured breathing. Weakness. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. |
Skin | MAY BE ABSORBED! Redness. Further see Inhalation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . |
Eyes | Redness. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Further see Inhalation. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. |
According to UN GHS Criteria Transportation |
STORAGE | |
Fireproof. Separated from strong oxidants, strong bases, strong acids and food and feedstuffs. Well closed. Cool. Ventilation along the floor. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
CHLOROACETONITRILE | ICSC: 0844 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C2H2ClN / ClCH2CN |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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ENVIRONMENT |
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The substance is toxic to aquatic organisms. |
NOTES |
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The symptoms of acute intoxication do not become manifest until a few hours. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. See ICSC 0088. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 23/24/25-51/53; S: (1/2)-45-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations Chloroacetonitrile (IARC Summary & Evaluation, Volume 71, 1999)