4-METHYLPYRIDINE | ICSC: 0803 (March 1999) |
4-Picoline gamma-picoline p-Picoline |
CAS #: 108-89-4 |
UN #: 2313 |
EC Number: 203-626-4 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 57°C explosive vapour/air mixtures may be formed. | NO open flames, NO sparks and NO smoking. Above 57°C use a closed system, ventilation and explosion-proof electrical equipment. | Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
PREVENT GENERATION OF MISTS! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Burning sensation. Cough. Dizziness. Drowsiness. Headache. Nausea. Sore throat. Unconsciousness. Weakness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | MAY BE ABSORBED! Dry skin. Redness. Burning sensation. Pain. Blisters. Further see Inhalation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . |
Eyes | Redness. Pain. Severe deep burns. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. Burning sensation. Diarrhoea. Vomiting. Further see Inhalation. | Do not eat, drink, or smoke during work. | Rinse mouth. Do NOT induce vomiting. Rest. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria Transportation |
STORAGE | |
Fireproof. Separated from strong oxidants. Well closed. | |
PACKAGING | |
Marine pollutant. |
4-METHYLPYRIDINE | ICSC: 0803 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C6H7N / (C5H4N)CH3 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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ENVIRONMENT |
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NOTES |
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See ICSCs 0801 and 0802. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T; R: 10-20/22-24-36/37/38; S: (1/2)-26-36-45 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations