STIBINE | ICSC: 0776 (November 2008) |
Antimony hydride Antimony trihydride Hydrogen antimonide |
CAS #: 7803-52-3 |
UN #: 2676 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Extremely flammable. Gives off irritating or toxic fumes (or gases) in a fire. Gas/air mixtures are explosive. Risk of fire and explosion on contact with ozone or nitric acid. | NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. | Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position. |
AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Headache. Weakness. Laboured breathing. Nausea. Weak and irregular pulse. Hemoglobinuria. | Use closed system or ventilation. | Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention. |
Skin | ON CONTACT WITH LIQUID: FROSTBITE. | Cold-insulating gloves. | ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer immediately for medical attention. |
Eyes | Redness. | Wear eye protection in combination with breathing protection. | Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention. |
Ingestion |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Ventilation. |
According to UN GHS Criteria DANGER
Extremely flammable gasFatal if inhaled May cause damage to respiratory tract and blood if inhaled Transportation |
STORAGE | |
Fireproof. Cool. | |
PACKAGING | |
STIBINE | ICSC: 0776 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: SbH3 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 0.1 ppm as TWA |
ENVIRONMENT |
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NOTES |
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Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C. Depending on the degree of exposure, periodic medical examination is suggested. The relation between odour and the occupational exposure limit cannot be indicated. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: Xn, N; R: 20/22-51/53; S: (2)-61; Note: A, 1 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations