1,2,3-TRICHLOROPROPANE | ICSC: 0683 (November 2016) |
Glycerol trichlorohydrin Allyl trichloride |
CAS #: 96-18-4 |
UN #: 2810 |
EC Number: 202-486-1 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 73°C explosive vapour/air mixtures may be formed. Risk of fire and explosion on contact with metals. | NO open flames. Above 73°C use a closed system, ventilation and explosion-proof electrical equipment. | Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
AVOID ALL CONTACT! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Headache. Drowsiness. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer immediately for medical attention. |
Skin | Dry skin. Redness. Tingling sensation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention if skin irritation occurs. |
Eyes | Redness. Pain. | Wear safety spectacles or eye protection in combination with breathing protection. | Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer for medical attention. |
Ingestion | Nausea. Headache. Vomiting. Diarrhoea. Drowsiness. Unconsciousness. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Toxic if swallowed, in contact with skin or if inhaledCauses eye irritation May cause cancer Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to liver and kidneys Harmful to aquatic life Transportation |
STORAGE | |
Separated from powdered metals and food and feedstuffs. Cool. Keep in a well-ventilated room. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. Marine pollutant. |
1,2,3-TRICHLOROPROPANE | ICSC: 0683 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C3H5Cl3 / CH2ClCHClCH2Cl |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 0.005 ppm as TWA; A2 (suspected human carcinogen). MAK: skin absorption (H); carcinogen category: 2 |
ENVIRONMENT |
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The substance is harmful to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to ground water contamination. |
NOTES |
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Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T; R: 45-60-20/21/22; S: 53-45; Note: D |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations