TETRAHYDROTHIOPHENE | ICSC: 0677 (March 1998) |
Tetramethylene sulfide Thiolane Thiophane Thiocyclopentane |
CAS #: 110-01-0 |
UN #: 2412 |
EC Number: 203-728-9 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Highly flammable. Heating will cause rise in pressure with risk of bursting. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive. | NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. | Use water spray, alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
SYMPTOMS | PREVENTION | FIRST AID | |
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Inhalation | Headache. Nausea. Dizziness. Palpitations. | Use closed system or ventilation. | Fresh air, rest. |
Skin | Protective gloves. | Rinse and then wash skin with water and soap. | |
Eyes | Wear safety spectacles. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. | |
Ingestion | Do not eat, drink, or smoke during work. | Rinse mouth. Rest. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. |
According to UN GHS Criteria Transportation |
STORAGE | |
Fireproof. Separated from strong oxidants. Cool. Store in an area without drain or sewer access. | |
PACKAGING | |
TETRAHYDROTHIOPHENE | ICSC: 0677 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C4H8S |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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MAK: 180 mg/m3, 50 ppm; peak limitation category: I(1); pregnancy risk group: C |
ENVIRONMENT |
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NOTES |
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ADDITIONAL INFORMATION | ||
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EC Classification Symbol: F, Xn; R: 11-20/21/22-36/38-52/53; S: (2)-16-23-36/37-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations