COPPER (II) ORTHOARSENATE | ICSC: 0648 (November 2016) |
Arsenic acid, copper salt Copper arsenate |
CAS #: 10103-61-4 |
UN #: 1557 |
EC Number: 233-286-2 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. | In case of fire in the surroundings, use appropriate extinguishing media. |
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Headache. Laboured breathing. Weakness. See Ingestion. | Use closed system, ventilation or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention . | |
Eyes | Redness. Pain. | Wear face shield or eye protection in combination with breathing protection if powder. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. Diarrhoea. Vomiting. Burning sensation behind the breastbone and in the mouth. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer immediately for medical attention. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Vacuum spilled material with specialist equipment. Carefully collect remainder. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Toxic if swallowedCauses eye irritation May cause cancer Suspected of damaging fertility or the unborn child Causes damage to organs Causes damage to organs through prolonged or repeated exposure May cause long lasting harmful effects to aquatic life Transportation |
STORAGE | |
Separated from acids and food and feedstuffs. Cool. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. Marine pollutant. |
COPPER (II) ORTHOARSENATE | ICSC: 0648 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: As2Cu3H8O12 / Cu3(AsO4)2.4H2O |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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MAK: skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3A. EU-OEL: (inhalable fraction): 0.01 mg/m3 as TWA; (see Notes) |
ENVIRONMENT |
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This substance may be hazardous to the environment. Special attention should be given to water quality. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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Do NOT take working clothes home. Depending on the degree of exposure, periodic medical examination is suggested. For the copper smelting sector, the EU OEL value shall apply from 11 July 2023. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 45-23/25-50/53; S: 53-45-60-61; Note: A, E |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations