2,4-TOLUENEDIAMINE | ICSC: 0582 (April 2014) |
2,4-Toluylenediamine 4-Methyl-m-phenylenediamine 2,4-Diaminotoluene 2,4-TDA |
CAS #: 95-80-7 |
UN #: 1709 |
EC Number: 202-453-1 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air. | NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. | Use water spray, foam, powder, carbon dioxide. |
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. | Use local exhaust or breathing protection. | Fresh air, rest. |
Skin | MAY BE ABSORBED! Redness. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. |
Eyes | Redness. Pain. | Wear safety goggles (if molten) or face shield. | Rinse with plenty of water (remove contact lenses if easily possible). |
Ingestion | Do not eat, drink, or smoke during work. | Rinse mouth. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Toxic if swallowedHarmful in contact with skin May cause an allergic skin reaction Suspected of causing genetic defects May cause cancer Suspected of damaging fertility or the unborn child May cause damage to liver and kidneys through prolonged or repeated exposure Toxic to aquatic life with long lasting effects Transportation |
STORAGE | |
Well closed. Separated from oxidants and acids. Separated from food and feedstuffs. Store in an area without drain or sewer access. Do NOT store or transport in containers made from aluminium or copper and its alloys. Provision to contain effluent from fire extinguishing. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
2,4-TOLUENEDIAMINE | ICSC: 0582 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C7H10N2 / CH3C6H3(NH2)2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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MAK: (vapour and aerosol): sensitization of skin (SH); skin absorption (H); carcinogen category: 2; germ cell mutagen group: 3B |
ENVIRONMENT |
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The substance is toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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Do NOT take working clothes home. Often transported in the molten state. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 45-21-25-43-48/22-62-68-51/53; S: 53-45-61; Note: E |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations