1-CHLORO-2,4-DINITROBENZENE | ICSC: 0416 (June 2015) |
1,3-Dinitro-4-chlorobenzene 2,4-Dinitrophenyl chloride DNCB |
CAS #: 97-00-7 |
UN #: 3441 |
EC Number: 202-551-4 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Finely dispersed particles form explosive mixtures in air. | NO open flames. NO contact with incompatible substances. See Chemical Dangers. Do NOT expose to friction or shock. | Use water spray, foam, dry powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position. |
PREVENT DISPERSION OF DUST! AVOID ALL CONTACT! FIRST AID: USE PERSONAL PROTECTION. | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Blue lips, fingernails and skin. Dizziness. Headache. Laboured breathing. Nausea. Vomiting. Blurred vision. | Use local exhaust or breathing protection. | Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. |
Skin | MAY BE ABSORBED! Redness. Pain. Further see Inhalation. | Protective gloves. Protective clothing. | Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention . |
Eyes | Redness. Pain. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal pain. Further see Inhalation. | Do not eat, drink, or smoke during work. Wash hands before eating. | Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Vacuum with specialist equipment (See Notes) or carefully sweep into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Fatal in contact with skinHarmful if swallowed Causes skin and eye irritation May cause an allergic skin reaction May cause damage to blood Very toxic to aquatic life with long lasting effects Transportation |
STORAGE | |
Fireproof. Separated from strong oxidants, strong bases, strong reducing agents, food and feedstuffs and ammonia. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. Marine pollutant. |
1-CHLORO-2,4-DINITROBENZENE | ICSC: 0416 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: C6H3ClN2O4 / C6H3Cl(NO2)2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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MAK sensitization of skin (SH) |
ENVIRONMENT |
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The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
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NEVER use a domestic-type vacuum cleaner to vacuum the substance, only use specialist equipment. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: T, N; R: 23/24/25-33-50/53; S: (1/2)-28-36/37-45-60-61; Note: C |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations