meta-TOLUIDINE | ICSC: 0342 (November 2009) |
3-Aminotoluene m-Methylaniline 1-Amino-3-methylbenzene |
CAS #: 108-44-1 |
UN #: 1708 |
EC Number: 203-583-1 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
---|---|---|---|
FIRE & EXPLOSION | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 85°C explosive vapour/air mixtures may be formed. | NO open flames. Above 85°C use a closed system and ventilation. | Use water spray, foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR! | |||
---|---|---|---|
SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Blue lips, fingernails and skin. Confusion. Dizziness. Headache. Shortness of breath. Weakness. Convulsions. Nausea. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Artificial respiration may be needed. Refer immediately for medical attention. |
Skin | Redness. Further see Inhalation. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer immediately for medical attention. |
Eyes | Redness. Pain. | Wear safety goggles. | Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention. |
Ingestion | Blue lips, fingernails and skin. Dizziness. Headache. Laboured breathing. Further see Inhalation. | Do not eat, drink, or smoke during work. | Rinse mouth. Refer immediately for medical attention. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
---|---|
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria WARNING
Combustible liquidHarmful if swallowed May be harmful in contact with skin Causes eye irritation May cause damage to blood Very toxic to aquatic life Transportation |
STORAGE | |
Provision to contain effluent from fire extinguishing. Separated from strong oxidants, strong acids and food and feedstuffs. Well closed. Ventilation along the floor. Keep in the dark. Store in an area without drain or sewer access. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
meta-TOLUIDINE | ICSC: 0342 |
PHYSICAL & CHEMICAL INFORMATION | |
---|---|
Physical State; Appearance
Physical dangers
Chemical dangers
|
Formula: C7H9N / C6H4CH3NH2 |
EXPOSURE & HEALTH EFFECTS | |
---|---|
Routes of exposure
Effects of short-term exposure
|
Inhalation risk
Effects of long-term or repeated exposure
|
OCCUPATIONAL EXPOSURE LIMITS |
---|
TLV: 2 ppm as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued |
ENVIRONMENT |
---|
The substance is very toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
NOTES |
---|
Depending on the degree of exposure, periodic medical examination is suggested. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. The odour warning when the exposure limit value is exceeded is insufficient. Do NOT take working clothes home. See ICSCs 0341 and 0343. |
ADDITIONAL INFORMATION | ||
---|---|---|
EC Classification Symbol: T, N; R: 23/24/25-33-50; S: (1/2)-28-36/37-45-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations