TRICHLOROMETHANESULFENYL CHLORIDE | ICSC: 0311 (June 2003) |
Trichloromethanesulfenyl chloride Trichlormethyl sulfur chloride Thiocarbonyl tetrachloride Trichloromethyl sulfochloride Perchloromethyl mercaptan |
CAS #: 594-42-3 |
UN #: 1670 |
EC Number: 209-840-4 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. | In case of fire in the surroundings, use appropriate extinguishing media. |
STRICT HYGIENE! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Laboured breathing. Nausea. Vomiting. Convulsions. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. |
Skin | Redness. Pain. | Protective gloves. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . |
Eyes | Redness. Pain. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Abdominal cramps. Further see Inhalation. | Do not eat, drink, or smoke during work. | Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria Transportation |
STORAGE | |
Separated from food and feedstuffs. See Chemical Dangers. Well closed. | |
PACKAGING | |
Unbreakable packaging. Put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs. Marine pollutant. |
TRICHLOROMETHANESULFENYL CHLORIDE | ICSC: 0311 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: CCl4S / CCl3SCl |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 0.1 ppm as TWA |
ENVIRONMENT |
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Environmental effects from the substance have not been investigated adequately. |
NOTES |
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The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered. The name Perchloromethyl mercaptan is also used for a compound with CAS number 75-70-7 (CCl_3SH). |
ADDITIONAL INFORMATION | ||
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EC Classification |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations