ETHYLENEDIAMINE | ICSC: 0269 (May 2018) |
1,2-Ethanediamine Dimethylenediamine 1,2-Diaminoethane |
CAS #: 107-15-3 |
UN #: 1604 |
EC Number: 203-468-6 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 34°C explosive vapour/air mixtures may be formed. | NO open flames, NO sparks and NO smoking. Above 34°C use a closed system, ventilation and explosion-proof electrical equipment. | Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Cough. Sore throat. Shortness of breath. Burning sensation. Wheezing. Shortness of breath. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer immediately for medical attention. |
Skin | Redness. Pain. Burning sensation. Skin burns. | Protective gloves. Protective clothing. | Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer immediately for medical attention. |
Eyes | Redness. Pain. Blurred vision. Severe burns. | Wear face shield or eye protection in combination with breathing protection. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Burns in mouth and throat. Sore throat. Burning sensation. Abdominal pain. Shock or collapse. | Do not eat, drink, or smoke during work. | Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer immediately for medical attention. |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Remove all ignition sources. Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Collect the spilled substance into containers. The container should be made of the same material as the original container. |
According to UN GHS Criteria DANGER
Flammable liquid and vapourHarmful if swallowed or in contact with skin Causes severe skin burns and eye damage May cause an allergic skin reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled Transportation |
STORAGE | |
Fireproof. Separated from strong oxidants, acids, chlorinated organic compounds and food and feedstuffs. Cool. Well closed. Store only in original container. | |
PACKAGING | |
Do not transport with food and feedstuffs. |
ETHYLENEDIAMINE | ICSC: 0269 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: H2NCH2CH2NH2 / C2H8N2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 10 ppm as TWA; (skin); A4 (not classifiable as a human carcinogen). MAK sensitization of respiratory tract and skin (SAH) |
ENVIRONMENT |
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NOTES |
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The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Anyone who has shown symptoms of asthma due to this substance should avoid all further contact. Do NOT take working clothes home. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: C; R: 10-21/22-34-42/43; S: (1/2)-23-26-36/37/39-45 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations Ethylenediamine (CICADS 15, 1999)