1,1-DICHLOROETHANE | ICSC: 0249 (April 2017) |
Ethane, 1,1-dichloro- Ethylidene chloride |
CAS #: 75-34-3 |
UN #: 2362 |
EC Number: 200-863-5 |
ACUTE HAZARDS | PREVENTION | FIRE FIGHTING | |
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FIRE & EXPLOSION | Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive. | NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling. | Use water spray, foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. |
PREVENT GENERATION OF MISTS! | |||
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SYMPTOMS | PREVENTION | FIRST AID | |
Inhalation | Dizziness. Drowsiness. Lethargy. Nausea. Unconsciousness. | Use ventilation, local exhaust or breathing protection. | Fresh air, rest. Refer for medical attention. |
Skin | Dry skin. Roughness. | Protective gloves. | Remove contaminated clothes. Rinse skin with plenty of water or shower. |
Eyes | Redness. Pain. | Wear safety spectacles. | First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. |
Ingestion | Burning sensation. Further see Inhalation. | Do not eat, drink, or smoke during work. | Rinse mouth. Refer for medical attention . |
SPILLAGE DISPOSAL | CLASSIFICATION & LABELLING |
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Personal protection: self-contained breathing apparatus. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. |
According to UN GHS Criteria DANGER
Highly flammable liquid and vapourMay cause damage to liver and kidneys through prolonged or repeated exposure Harmful to aquatic life with long lasting effects Transportation |
STORAGE | |
Fireproof. See Chemical Dangers. Cool. | |
PACKAGING | |
Marine pollutant. |
1,1-DICHLOROETHANE | ICSC: 0249 |
PHYSICAL & CHEMICAL INFORMATION | |
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Physical State; Appearance
Physical dangers
Chemical dangers
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Formula: CH3CHCl2 |
EXPOSURE & HEALTH EFFECTS | |
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Routes of exposure
Effects of short-term exposure
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Inhalation risk
Effects of long-term or repeated exposure
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OCCUPATIONAL EXPOSURE LIMITS |
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TLV: 100 ppm as TWA; A4 (not classifiable as a human carcinogen). MAK: 205 mg/m3, 50 ppm; peak limitation category: II(2); skin absorption (H); pregnancy risk group: C; carcinogen category: 3. EU-OEL: 412 mg/m3, 100 ppm as TWA; (skin) |
ENVIRONMENT |
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The substance is harmful to aquatic organisms. The substance may cause long-term effects in the aquatic environment. |
NOTES |
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Do NOT use in the vicinity of a fire or a hot surface, or during welding. |
ADDITIONAL INFORMATION | ||
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EC Classification Symbol: F, Xn; R: 11-22-36/37-52/53; S: (2)-16-23-61 |
All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material. | |
See Also: Toxicological Abbreviations 1,1-DICHLOROETHANE (JECFA Evaluation)