|CHLOROACETIC ACID||ICSC: 0235 (November 2016)|
| CAS #: 79-11-8
| UN #: 1751
|EC Number: 201-178-4
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames. NO contact with incompatible substances. See Chemical Dangers.||Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR! FIRST AID: USE PERSONAL PROTECTION. See Notes.|
|Inhalation||Sore throat. Cough. Shortness of breath. Burning sensation behind the breastbone. Laboured breathing. Symptoms may be delayed. See Notes. Further see Ingestion.||Use local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Pain. Skin burns. Further see Ingestion.||Protective gloves. Protective clothing.||Wear protective gloves when administering first aid. First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. See Notes. Refer immediately for medical attention.|
|Eyes||Redness. Pain. Severe burns.||Wear face shield or eye protection in combination with breathing protection if powder.||Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.|
|Ingestion||Burns in mouth and throat. Abdominal pain. Vomiting. Diarrhoea. Convulsions. Shock or collapse. Unconsciousness.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention. See Notes.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERMay be corrosive to metals
Toxic if swallowed or in contact with skin
Causes severe skin burns and eye damage
May cause respiratory irritation
Causes damage to organs
Very toxic to aquatic life
|Separated from incompatible materials and food and feedstuffs. See Chemical Dangers. Dry. Store only in original container. Well closed. Ventilation along the floor. Store in an area without drain or sewer access.|
|Do not transport with food and feedstuffs.|
|CHLOROACETIC ACID||ICSC: 0235|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C2H3ClO2 / ClCH2COOH
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.5 ppm as TWA; (skin); A4 (not classifiable as a human carcinogen).
MAK: 2.0 mg/m3, 0.5 ppm; peak limitation category: I(2); pregnancy risk group: C
|The substance is very toxic to aquatic organisms.|
|After skin contact, immediately rinsing with plenty of water is needed. Alternatively, emergency baths with 3 - 5 % sodium bicarbonate can be used to submerge the exposed skin.
When > 5 % of the skin surface is affected a severe and even a life-threatening intoxication may occur.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Consult a poison information centre or an expert for further information.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.
Other melting points: 63°C (alpha form), 56.2°C (beta form), 52.5°C (gamma form).
Other UN numbers: 1750 Chloroacetic acid, solution; 3250 Chloroacetic acid, molten.
Symbol: T, C, N; R: 23/24/25-34-50; S: (1/2)-26-36/37/39-45-61-63
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations