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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible.
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NO open flames.
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Foam, water spray, dry powder, carbon dioxide.
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| EXPLOSION |
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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| Inhalation |
Dizziness. Headache.
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Local exhaust.
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Fresh air, rest. Refer for medical attention.
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| Skin |
Dry skin.
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Protective gloves.
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Remove contaminated clothes. Rinse skin with plenty of water or shower.
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| Eyes |
Redness.
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Safety spectacles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Diarrhoea. Nausea.
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Do not eat, drink, or smoke during work.
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Do NOT induce vomiting. Refer for medical attention. See Notes.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
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EU Classification Symbol: T R: 45 S: 53-45 Note: [H, L] UN Classification | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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Separated from strong oxidants.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: AMBER VISCOUS LIQUID, WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: Reacts with strong oxidants causing fire and explosion hazard. OCCUPATIONAL EXPOSURE LIMITS: TLV: (oil mist, mineral) 5 mg/m³ Intended change (ACGIH 2001). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance is mildly irritating to the skin. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 150-600°C Relative density (water = 1): about 0.84 - 0.94 at 15°C |
Flash point: > 124°C Octanol/water partition coefficient as log Pow: 3.9 - 6 (calculated) | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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A raffinate contains C20-C50 hydrocarbons with a viscosity of less than 19 cSt at 40°C (100 SUS at 100°F). Depending on the raw material and the production processes, the composition and physical properties of this solvent can vary considerably. The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days have passed and they are aggravated by physical effort. Note L: the EU classification as carcinogen (R45) does not apply if it can be shown that DMSO extract (IP 346) is below 3% by volume. PY8040500 refers to mineral oil, petroleum distillate, solvent refined (mild) heavy paraffinic; PY8040501 refers to mineral oil, petroleum distillate, solvent refined (severe) heavy paraffinic. Card has been partly updated in April 2005. See section EU classification. | |||
| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 1999 | |||
See Also:
Toxicological Abbreviations