ICSC 1339 - DICYCLOHEXYLAMINE

DICYCLOHEXYLAMINE	ICSC: 1339 (October 1999)
N,N-Dicyclohexylamine N-Cyclohexylcyclohexanamine Dodecahydrodiphenylamine

CAS #: 101-83-7

UN #: 2565

EC Number: 202-980-7

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Symptoms may be delayed. See Notes.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Skin	Pain. Redness. Blisters. Skin burns.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
Eyes	Pain. Redness. Severe deep burns.	Wear face shield.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Burning sensation. Abdominal pain. Shock or collapse.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention .

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Cautiously neutralize remainder. Then wash away with plenty of water.	According to UN GHS Criteria Transportation UN Classification UN Hazard Class: 8; UN Pack Group: III
STORAGE
Separated from strong oxidants, strong acids and food and feedstuffs.
PACKAGING
Do not transport with food and feedstuffs.

DICYCLOHEXYLAMINE

ICSC: 1339

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR. Physical dangers Chemical dangers Decomposes on burning. This produces toxic fumes including nitrogen oxides. The substance is a strong base. It reacts violently with acid and is corrosive. Reacts with strong oxidants.	Formula: C₁₂H₂₃N / C₆H₁₁NHC₆H₁₁ Molecular mass: 181.4 Boiling point: 256°C Melting point: -0.1°C Relative density (water = 1): 0.9 Solubility in water, g/100ml at 25°C: 0.08 Vapour pressure, kPa at 37.7°C: 1.6 Relative vapour density (air = 1): 6.25 Flash point: 105°C o.c. Auto-ignition temperature: 255°C Explosive limits, vol% in air: 0.9-6.9 Octanol/water partition coefficient as log Pow: 3.5

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.

Physical dangers

Chemical dangers
Decomposes on burning. This produces toxic fumes including nitrogen oxides. The substance is a strong base. It reacts violently with acid and is corrosive. Reacts with strong oxidants.

Formula: C₁₂H₂₃N / C₆H₁₁NHC₆H₁₁
Molecular mass: 181.4
Boiling point: 256°C
Melting point: -0.1°C
Relative density (water = 1): 0.9
Solubility in water, g/100ml at 25°C: 0.08
Vapour pressure, kPa at 37.7°C: 1.6
Relative vapour density (air = 1): 6.25
Flash point: 105°C o.c.
Auto-ignition temperature: 255°C
Explosive limits, vol% in air: 0.9-6.9
Octanol/water partition coefficient as log Pow: 3.5

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour and by ingestion. Effects of short-term exposure The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.	Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C. Effects of long-term or repeated exposure

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

Effects of short-term exposure
The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.

Inhalation risk
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.

Effects of long-term or repeated exposure

OCCUPATIONAL EXPOSURE LIMITS
MAK skin absorption (H)

ENVIRONMENT
The substance is harmful to aquatic organisms.

NOTES
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential. Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.

ADDITIONAL INFORMATION

EC Classification
Symbol: C, N; R: 22-34-50/53; S: (1/2)-26-36/37/39-45-60-61

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    See Also:
       Toxicological Abbreviations