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PROPAQUIZAFOP
ICSC: 1271
Peer-Review Status: 09.06.2011 Validated
2-Isopropylideneamino-oxyethyl (R)-2-(4-(6-chloroquinoxalin-2-yloxy)phenoxy)propionate
(R)-2-(((1-Methylethylidene)amino)oxy)ethyl 2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)propanoate 
CAS #: 111479-05-1 RTECS #: UA2458258
UN #: 3077
    Formula: C22H22ClN3O5
Molecular mass: 443.9

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.    In case of fire in the surroundings, use appropriate extinguishing media. 
EXPLOSION      
 
EXPOSURE   STRICT HYGIENE! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!   
Inhalation See Notes.  Use local exhaust or breathing protection.  Fresh air, rest. Seek medical attention if you feel unwell. 
Skin See Notes.  Protective gloves. Protective clothing.  Remove contaminated clothes. Rinse and then wash skin with water and soap. 
Eyes Redness.  Wear safety spectacles.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion See Notes.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Seek medical attention if you feel unwell. 

SPILLAGE DISPOSAL
PACKAGING & LABELLING
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.  Do not transport with food and feedstuffs. 
EC Classification
 
UN Classification
UN Hazard Class: 9; UN Pack Group: III 
GHS Classification
Signal: Warning
Harmful if inhaled
May be harmful if swallowed
Very toxic to aquatic life with long lasting effects 
excl mark;warnenviro;aqua

EMERGENCY RESPONSE SAFE STORAGE
  Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Store in an area without drain or sewer access. 

IMPORTANT DATA
Physical State; Appearance
COLOURLESS-TO-BROWN CRYSTALS. 

Physical dangers
 

Chemical dangers
Decomposes on burning. This produces toxic and corrosive fumes including hydrogen chloride and nitrogen oxides. 

Occupational exposure limits
TLV (NOT-ESTABLISHED):.
MAK (not established):. 

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol. 

Inhalation risk
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed, especially if powdered. 

Effects of short-term exposure
The substance is mildly irritating to the eyes. 

Effects of long-term or repeated exposure
See Notes. 


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Melting point: 62-64°C
Relative density (water = 1): 1.3
Solubility in water, g/100ml at 20°C: 0.06 (very poor)
Vapour pressure at 20°C: negligible
Octanol/water partition coefficient as log Pow: 4.6  
The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal. 

NOTES
Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
If the substance is formulated with solvents also consult the ICSCs of these materials.
Carrier solvents used in commercial formulations may change physical and toxicological properties. 

ADDITIONAL INFORMATION
 

IPCS
International
Programme on
Chemical Safety
WHO ILO EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004-2012
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.


    See Also:
       Toxicological Abbreviations