|CAS #: 35400-43-2||O-Ethyl O-4-(methylthio)phenyl S-propyl phosphorodithioate
O-Ethyl O-4-(methylthio)phenyl S-propyl dithiophosphate
O-Ethyl O-4-(methylthio)phenyl phosphorodithioic acid S-propyl ester
| UN #: 3018
| EINECS #: 252-545-0
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.||Use alcohol-resistant foam, powder, carbon dioxide.|
|AVOID ALL CONTACT! FIRST AID: USE PERSONAL PROTECTION. IN ALL CASES CONSULT A DOCTOR!|
|SYMPTOMS||ACUTE HAZARDS||FIRST AID|
|Inhalation||Pupillary constriction, muscle cramp, excessive salivation. Headache. Sweating. Dizziness. Nausea. Diarrhoea. Vomiting. Laboured breathing. Unconsciousness. Symptoms may be delayed.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Blurred vision.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
According to UN GHS Criteria
DANGERFatal if inhaled
Toxic if swallowed or in contact with skin
Causes damage to nervous system
Causes damage to the nervous system through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects
|Separated from food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. Well closed.|
|Do not transport with food and feedstuffs.
Severe marine pollutant.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|Occupational exposure limits|
|TLV: 0.1 mg/m3, ppm, as TWA; (skin); A4 (not classifiable as a human carcinogen); BEI issued|
|The substance is very toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. This substance may be hazardous to the environment. Special attention should be given to fish and wildlife. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|
See Also: Toxicological Abbreviations