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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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| EXPLOSION |
Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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| EXPOSURE |
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PREVENT DISPERSION OF DUST!
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| Inhalation |
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Local exhaust or breathing protection.
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Fresh air, rest.
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| Skin |
Redness. Burning sensation. Pain.
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse and then wash skin with water and soap.
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| Eyes |
Redness. Pain.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work.
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Rinse mouth. Give plenty of water to drink. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. Personal protection: P2 filter respirator for harmful particles.
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EU Classification Symbol: Xn R: 22-36-43 S: (2-)-24/25-26-37/39-46 UN Classification | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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NFPA Code: H2; F1; R0;
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Separated from strong oxidants, strong bases, acid anhydrides, acid chlorides.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: WHITE TO TAN SOLID IN VARIOUS FORMS, WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. CHEMICAL DANGERS: Reacts with strong oxidants, strong bases, acid anhydrides and acid chlorides. The solution in water is a weak acid. OCCUPATIONAL EXPOSURE LIMITS: TLV: 5 mg/m³ as TWA; (ACGIH 2004). MAK not established. |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by ingestion. INHALATION RISK: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes and the skin. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the skin, resulting in depigmentation. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 243°C Melting point: 57°C Density: 1.6 g/cm³ Solubility in water, g/100 ml at 25°C: 4 Relative vapour density (air = 1): 4.3 |
Flash point: 132°C o.c. Auto-ignition temperature: 421°C Octanol/water partition coefficient as log Pow: 1.58 | ||
| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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Do NOT take working clothes home.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations