TYPES OF HAZARD
|ACUTE HAZARDS / SYMPTOMS||PREVENTION||FIRST AID / FIRE-FIGHTING|
|FIRE||Combustible.||NO open flames.||Use water spray, foam, powder, carbon dioxide.|
|EXPOSURE||STRICT HYGIENE!||IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Convulsions. Laboured breathing. Pupillary constriction, muscle cramp, excessive salivation. Sweating.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! See Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||See Inhalation.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||See Inhalation. Abdominal cramps. Diarrhoea. Vomiting.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .|
|PACKAGING & LABELLING|
|Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus.||
Symbol: T+, N; R: 27/28-50/53; S: (1/2)-28-36/37-45-60-61
UN Hazard Class: 6.1; UN Pack Group: I
Fatal if swallowed, in contact with skin or if inhaled
Causes damage to nervous system
Causes damage to the nervous system through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects
|EMERGENCY RESPONSE||SAFE STORAGE|
|Transport Emergency Card: TEC (R)-61GT6-I.||Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.|
Physical State; Appearance
COLOURLESS-TO-YELLOW LIQUID WITH CHARACTERISTIC ODOUR.
Occupational exposure limits
Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin, through the eyes and by ingestion.
Effects of short-term exposure
Effects of long-term or repeated exposure
|PHYSICAL PROPERTIES||ENVIRONMENTAL DATA|
Melting point: -42.9°C
Relative density (water = 1): 1.2
Solubility in water: none
Vapour pressure, Pa at 20°C: 0.1
Flash point: 160°C o.c.
Octanol/water partition coefficient as log Pow: 3.9
|The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment. Special attention should be given to birds and bees. This substance does enter the environment under normal use. Great care, however, should be taken to avoid any additional release, for example through inappropriate disposal.|
Do NOT take working clothes home.
Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Card has been partially updated in October 2005: see Occupational Exposure Limits; EU Classification; Emergency Response.
Card has been partially updated in November 2008: see Ingestion First Aid; Occupational Exposure Limits; Storage.
Card has been partially updated in April 2013: see GHS classification.
See Also: Toxicological Abbreviations Phorate (Pesticide residues in food: 1977 evaluations) Phorate (Pesticide residues in food: 1982 evaluations) Phorate (Pesticide residues in food: 1984 evaluations) Phorate (Pesticide residues in food: 1985 evaluations Part II Toxicology) Phorate (Pesticide residues in food: 1994 evaluations Part II Toxicology) Phorate (Pesticide residues in food: 1996 evaluations Part II Toxicological)