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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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| Inhalation |
Cough. Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest.
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| Skin |
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Protective gloves.
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Remove contaminated clothes. Rinse skin with plenty of water or shower.
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| Eyes |
Redness. Pain.
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Safety goggles, or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Abdominal pain. Diarrhoea. Nausea. Vomiting.
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Do not eat, drink, or smoke during work.
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Give plenty of water to drink. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Sweep spilled substance into coveredcontainers. Carefully collect remainder. then remove to safe place. Do NOT let this chemical enter the environment. Personal protection: P2 filter respirator for harmful particles.
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Do not transport with food and feedstuffs. EU Classification UN Classification UN Hazard Class: 8 UN Pack Group: III | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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Transport Emergency Card: TEC (R)-80GC2-II+III
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Separated from incompatible materials, food and feedstuffs. Dry.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS OR WHITE CRYSTALS CHEMICAL DANGERS: The substance decomposes on heating producing toxic and corrosive gases. The substance is a strong reducing agent and reacts with oxidants such as nitrates and peroxides, and bases. OCCUPATIONAL EXPOSURE LIMITS: TLV: (as Sn, Oxide and inorganic compounds, except tin hydride) 2 mg/m³ as TWA; (ACGIH 2004). EU OEL: (tin inorganic compounds, as Sn) 2 mg/m³ as TWA; (EU 2004). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: A harmful concentration of airborne particles can be reached quickly when dispersed. EFFECTS OF SHORT-TERM EXPOSURE: The substance is irritating to the eyes and the respiratory tract. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point (decomposes): 652°C Melting point: 246.8°C Density: 3.95 g/cm³ Solubility in water, g/100 ml at 20°C: 90 |
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| ENVIRONMENTAL DATA | |||
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The substance is harmful to aquatic organisms.
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| NOTES | |||
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 1999 | |||
See Also:
Toxicological Abbreviations