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p-NITROTOLUENE
ICSC: 0932
Peer-Review Status: 13.04.2000 Validated
4-Nitrotoluene
1-Methyl-4-nitrobenzene
p-Methylnitrobenzene
PNT 
CAS #: 99-99-0 RTECS #: XT3325000
UN #: 1664
EC #: 609-006-00-3
EINECS #: 202-808-0
    Formula: C7H7NO2 / C6H4(CH3)NO2
Molecular mass: 137.1

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Combustible.  NO open flames. NO contact with oxidizing agents.  Use water spray, powder, foam, carbon dioxide. 
EXPLOSION Risk of fire and explosion on contact with acids or oxidizing agents.    In case of fire: keep drums, etc., cool by spraying with water. 
 
EXPOSURE   PREVENT DISPERSION OF DUST! STRICT HYGIENE!   
Inhalation Headache. Blue lips, fingernails and skin. Dizziness. Laboured breathing.  Use local exhaust or breathing protection.  Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. 
Skin MAY BE ABSORBED! Further see Inhalation.  Protective gloves. Protective clothing.  Rinse and then wash skin with water and soap. Refer for medical attention . Wear protective gloves when administering first aid. 
Eyes Redness. Pain.  Wear safety goggles, face shield or eye protection in combination with breathing protection.  First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. 
Ingestion Abdominal pain. Further see Inhalation.  Do not eat, drink, or smoke during work. Wash hands before eating.  Rinse mouth. Refer for medical attention . 

SPILLAGE DISPOSAL
PACKAGING & LABELLING
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.  Do not transport with food and feedstuffs.
Marine pollutant. 
EC Classification
Symbol: T, N; R: 23/24/25-33-51/53; S: (1/2)-28-37-45-61; Note: C 
UN Classification
UN Hazard Class: 6.1; UN Pack Group: II 
GHS Classification
 

EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-61S1664-S or 61GT2-II.
NFPA Code: H3; F1; R0. 
Separated from food and feedstuffs. See Chemical Dangers. Well closed. 

IMPORTANT DATA
Physical State; Appearance
COLOURLESS-TO-YELLOW CRYSTALS WITH CHARACTERISTIC ODOUR. 

Physical dangers
 

Chemical dangers
Decomposes on heating. This produces toxic fumes of nitrogen oxides. Reacts violently with strong oxidants and sulfuric acid. This generates fire and explosion hazard. Attacks some forms of plastic, rubber and coatings. 

Occupational exposure limits
TLV: 2ppm as TWA; (skin); BEI issued; (ACGIH 2005).
MAK: Carcinogen category: 3B; Skin absorption (H); (DFG 2008). 

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. 

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered. 

Effects of short-term exposure
The substance is irritating to the eyes. The substance may cause effects on the blood. This may result in formation of methaemoglobin. The effects may be delayed. Medical observation is indicated. 

Effects of long-term or repeated exposure
The substance may have effects on the blood, liver and testes. 


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 238°C
Melting point: 53-54°C
Density: 1.29 g/cm³
Solubility in water, g/100ml at 20°C: 0.035
Vapour pressure, kPa at 20°C: 0.016
Relative vapour density (air = 1): 4.72
Flash point: 103°C c.c.
Auto-ignition temperature: 450°C
Octanol/water partition coefficient as log Pow: 2.41  
The substance is toxic to aquatic organisms. The substance may cause long-term effects in the aquatic environment. 

NOTES
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Depending on the degree of exposure, periodic medical examination is suggested.
Card has been partially updated in November 2008: see Occupational Exposure Limits. 

ADDITIONAL INFORMATION
 

IPCS
International
Programme on
Chemical Safety
WHO ILO EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004-2012
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.
    See Also:
       Toxicological Abbreviations