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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible.
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NO open flames.
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Powder, alcohol-resistant foam, water spray, carbon dioxide.
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| EXPLOSION |
Above 71°C explosive vapour/air mixtures may be formed.
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Above 71°C use a closed system, ventilation.
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| EXPOSURE |
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PREVENT GENERATION OF MISTS!
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| Inhalation |
Cough. Headache. Dizziness. Drowsiness. Nausea.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest. Refer for medical attention.
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| Skin |
MAY BE ABSORBED! Redness. Dry skin.
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse and then wash skin with water and soap.
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| Eyes |
Redness.
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Safety goggles.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Burning sensation in the throat and chest. Vomiting. (Further see Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth. Give plenty of water to drink. Do NOT induce vomiting. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours.)
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EU Classification Symbol: Xn R: 20/21 S: (2-)-24 UN Classification | |||||||
| EMERGENCY RESPONSE | STORAGE | |||||||
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NFPA Code: H 1; F 2; R 0;
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Separated from strong oxidants, and strong bases. Cool. Keep in the dark.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR. CHEMICAL DANGERS: The substance can presumably form explosive peroxides. Reacts with strong oxidants and strong bases, causing fire and explosion hazard. OCCUPATIONAL EXPOSURE LIMITS: TLV: 20 ppm as TWA; A3; (ACGIH 2003). MAK: 20 ppm, 130 mg/m³, H; Peak limitation category: II(4); Pregnancy risk group: C; (DFG 2003). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion. EFFECTS OF SHORT-TERM EXPOSURE: The vapour is irritating to the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system. Exposure far above the OEL may result in unconsciousness. The substance may cause effects on the blood, resulting in lesions of blood cells and kidney impairment. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The liquid defats the skin. The substance may have effects on the blood, resulting in anaemia and kidney impairment. | ||
| PHYSICAL PROPERTIES | |||
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Boiling point: 192°C Melting point: -64°C Relative density (water = 1): 0.94 Solubility in water: moderate (1.7 g/100 ml at 20°C) Vapour pressure, Pa at 20°C: 31 Relative vapour density (air = 1): 5.5 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.00 Flash point: 71°C c.c. Auto-ignition temperature: 340°C Explosive limits, vol% in air: 0.9 (93°C) - 8.5 (135°C) Octanol/water partition coefficient as log Pow: 1.51 | ||
| ENVIRONMENTAL DATA | |||
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The substance is harmful to aquatic organisms.
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| NOTES | |||
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Check for peroxides prior to distillation; eliminate if found.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 1999 | |||
See Also:
Toxicological Abbreviations