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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Combustible.
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Water spray, powder. In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
Finely dispersed particles form explosive mixtures in air.
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Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
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| EXPOSURE |
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AVOID ALL CONTACT!
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| Inhalation |
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Local exhaust or breathing protection.
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Fresh air, rest.
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| Skin |
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse and then wash skin with water and soap.
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| Eyes |
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Safety goggles, face shield or eye protection in combination with breathing protection. |
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
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Do not eat, drink, or smoke during work. Wash hands before eating.
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Rinse mouth.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: complete protective clothing including self-contained breathing apparatus.
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| EMERGENCY RESPONSE | STORAGE | |||||||
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Well closed.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: COLOURLESS TO YELLOW- BROWN FLUORESCENT FLAKES OR POWDER. PHYSICAL DANGERS: Dust explosion possible if in powder or granular form, mixed with air. OCCUPATIONAL EXPOSURE LIMITS: TLV: A2 (suspected human carcinogen); (ACGIH 2004). MAK: Carcinogen category: 2 (as pyrolysis product of organic materials) (DFG 2005). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation, through the skin and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: This substance is probably carcinogenic to humans. | ||
| PHYSICAL PROPERTIES | |||
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Sublimation point: 435°C Melting point: 162°C Relative density (water = 1): 1.274 Solubility in water: none Vapour pressure, Pa at 20°C: 292 |
Octanol/water partition coefficient as log Pow: 5.61 | ||
| ENVIRONMENTAL DATA | |||
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Bioaccumulation of this chemical may occur in seafood.
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| NOTES | |||
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This substance is one of many polycyclic aromatic hydrocarbons - standards are usually established for them as mixtures, e.g., coal tar pitch volatiles. However, it may be encountered as a laboratory chemical in its pure form. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. Do NOT take working clothes home. Tetraphene is a common name. Card has been partly updated in October 2005 and August 2006: see sections Occupational Exposure Limits, EU classification. | |||
| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations
Benz(a)Anthracene (IARC Summary & Evaluation, Volume 3, 1973)