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| TYPES OF HAZARD / EXPOSURE | ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
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In case of fire in the surroundings: use appropriate extinguishing media.
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| EXPLOSION |
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| EXPOSURE |
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PREVENT DISPERSION OF DUST!
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| Inhalation |
Cough. Laboured breathing. Shortness of breath. Sore throat.
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Local exhaust or breathing protection.
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Fresh air, rest. Half-upright position. Refer for medical attention.
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| Skin |
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Protective gloves.
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| Eyes |
Redness.
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Safety spectacles or eye protection in combination with breathing protection if powder.
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First rinse with plenty of water (remove contact lenses if easily possible).
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| Ingestion |
Sore throat.
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Do not eat, drink, or smoke during work.
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Rinse mouth.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING | |||||||
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Personal protection: P2 filter respirator for harmful particles. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
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| EMERGENCY RESPONSE | STORAGE | |||||||
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Dry.
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| IMPORTANT DATA | |||
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PHYSICAL STATE; APPEARANCE: PINK HYGROSCOPIC CRYSTALS. CHEMICAL DANGERS: The substance decomposes on heating producing sulfur oxides and manganese oxides. OCCUPATIONAL EXPOSURE LIMITS: TLV: as Mn 0.2 mg/m³ as TWA; (ACGIH 2006). MAK: (as Mn) (Inhalable fraction) 0.5 mg/m³; Pregnancy risk group: C; (DFG 2005). |
ROUTES OF EXPOSURE: The substance can be absorbed into the body by inhalation of its aerosol and by ingestion. INHALATION RISK: Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: The substance may have effects on the central nervous system. | ||
| PHYSICAL PROPERTIES | |||
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Relative density (water = 1): 2.95 Solubility in water, g/100 ml: 39.3 |
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| ENVIRONMENTAL DATA | |||
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| NOTES | |||
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Card has been partially updated in October 2006. See section Effects of Long-Term Exposure.
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| ADDITIONAL INFORMATION | |||
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| © IPCS, CEC 2005 | |||
See Also:
Toxicological Abbreviations