ALDICARB (ICSC)

ALDICARB	ICSC: 0094

Date of Peer Review: April 2004

2-Methyl-2-(methylthio)propionaldehyde O-(methylcarbamoyl)oxime
2-Methyl-2-(methylthio)propanal O-((methylamino)carbonyl)oxime

CAS #

116-06-3

C₇H₁₄N₂O₂S / CH₃SC(CH₃)₂CH=NOCONHCH₃

RTECS #

UE2275000

Molecular mass: 190.3

UN #

2757

EC #

006-017-00-X

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Powder, water spray, foam, carbon dioxide.
EXPLOSION

EXPOSURE		AVOID ALL CONTACT! AVOID EXPOSURE OF ADOLESCENTS AND CHILDREN!	IN ALL CASES CONSULT A DOCTOR!
Inhalation	Sweating. Pupillary constriction, muscle cramp, excessive salivation. Dizziness. Laboured breathing. Nausea. Vomiting. Convulsions. Unconsciousness.	Ventilation (not if powder), local exhaust, or breathing protection.	Fresh air, rest. Artificial respiration may be needed. Refer for medical attention. See Notes.
Skin	MAY BE ABSORBED! (Further see Inhalation).	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention. See Notes.
Eyes		Face shield, or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion	Abdominal cramps. Diarrhoea. Nausea. (Further see Inhalation).	Do not eat, drink, or smoke during work. Wash hands before eating.	Give a slurry of activated charcoal in water to drink. Refer for medical attention. See Notes.

SPILLAGE DISPOSAL

PACKAGING & LABELLING

Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment.

Do not transport with food and feedstuffs. Marine pollutant.
EU Classification
Symbol: T+, N
R: 24-26/28-50/53
S: (1/2-)-22-36/37-45-60-61
UN Classification
UN Hazard Class: 6.1
UN Pack Group: I

EMERGENCY RESPONSE

STORAGE

Transport Emergency Card: TEC (R)-61GT7-I

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the Commission of the European Communities © IPCS, CEC 1999

SEE IMPORTANT INFORMATION ON BACK

ALDICARB

ICSC: 0094

IMPORTANT DATA

PHYSICAL STATE; APPEARANCE:
COLOURLESS CRYSTALS.

CHEMICAL DANGERS:
On combustion, forms toxic fumes including nitrogen oxides, sulfur oxides.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established. MAK not established.

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

INHALATION RISK:
A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance may cause effects on the nervous system, resulting in convulsions and respiratory depression. Cholinesterase inhibitor. Exposure may result in death. The effects may be delayed. Medical observation is indicated.

PHYSICAL PROPERTIES

Decomposes below boiling point: see Notes
Melting point: 100°C
Solubility in water, g/100 ml at 25°C: 0.6
Vapour pressure, Pa at 25°C: 0.01

Octanol/water partition coefficient as log Pow: 1.36

ENVIRONMENTAL DATA

The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment; special attention should be given to birds, honey bees, mammals, soil organisms, water quality. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.

NOTES

Temperature of decomposition unknown in literature. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Do NOT take working clothes home.

ADDITIONAL INFORMATION

LEGAL NOTICE

Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information

    See Also:
       Toxicological Abbreviations
       Aldicarb (EHC 121, 1991)
       Aldicarb (HSG 64, 1991)
       Aldicarb (Pesticide residues in food: 1979 evaluations)
       Aldicarb (Pesticide residues in food: 1982 evaluations)
       Aldicarb (Pesticide residues in food: 1992 evaluations Part II Toxicology)
       Aldicarb (IARC Summary & Evaluation, Volume 53, 1991)